期刊
INORGANIC CHEMISTRY FRONTIERS
卷 6, 期 1, 页码 199-208出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qi00957k
关键词
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资金
- National Natural Science Foundation of China [21606081]
MXene is a new 2D transition metal carbide possessing metallic conductivity and hydrophilic surfaces. It has drawn widespread attention as a potential material for electrode use. However, the applications of MXene are limited by its property of low electrical capacity. In this paper, a novel MnO2/MXene composite is prepared by electrostatic self-assembly. Firstly, delaminated MnO2 nanosheets are obtained through the intercalation delamination of multilayered H-MnO2 in a cationic Gemini surfactant (Gem) solution, leading to a positively charged surface. Then, the positive MnO2 nanosheets are assembled on negative MXene nanosheets through electrostatic self-assembly to form a MnO2/MXene composite. The characterization results show that the MnO2 nanosheets are intimately assembled on the MXene nanosheets. As an electrode material, the MnO2/MXene composite displays a specific capacitance of 340 F g(-1) at 1 A g(-1), which is three times the performance of an MXene electrode. In addition, the MnO2/MXene electrode shows a high retention rate (90.3% retention at 10 A g(-1)) and good cycling life (87.6% of the initial specific capacitance is retained after 2000 cycles at 4 A g(-1)). The properties of the proposed composite are attributed to the excellent conductivity of MXene and the high specific capacitance of MnO2.
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