期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 52, 期 -, 页码 29-33出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2015.01.012
关键词
Hydrogen evolution reaction; Electrocatalysis; Ruthenium; Silicon nanowires; Nanostructure
资金
- National Basic Research Program of China (973 Program) [2012CB932903]
- Major Research Plan of National Natural Science Foundation of China [91433111]
- Qing Lan Project
- Collaborative Innovation Center of Suzhou Nano Science and Technology
- Innovative Research Teams of Jiangsu Higher Education Institutions
- Priority Academic Program Development of Jiangsu Higher Education
Ruthenium nanoparticles modified on silicon nanowires (Ru/SiNWs) were prepared by directly reducing Ru ions with Si-H bonds. The composites with different contents of Ru (denoted as Ru/SiNW-x, x means the relative molar ratio of Ru to SiNW) were evaluated as electrocatalysts for the hydrogen evolution reaction (HER). Ru/SiNW-42.9 showed an excellent electrocatalytic activity in the oxygen-free 0.5 M H2SO4 medium. The Tafel slope of Ru/SiNW-42.9 was 81 mV/decade, indicating that its catalytic effect was even better than pure Ru particles. SiNWs modified with proper content of Ru may be a promising electrocatalyst for HER. (C) 2015 Elsevier B.V. All rights reserved.
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