4.6 Article

Ru-modified silicon nanowires as electrocatalysts for hydrogen evolution reaction

期刊

ELECTROCHEMISTRY COMMUNICATIONS
卷 52, 期 -, 页码 29-33

出版社

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2015.01.012

关键词

Hydrogen evolution reaction; Electrocatalysis; Ruthenium; Silicon nanowires; Nanostructure

资金

  1. National Basic Research Program of China (973 Program) [2012CB932903]
  2. Major Research Plan of National Natural Science Foundation of China [91433111]
  3. Qing Lan Project
  4. Collaborative Innovation Center of Suzhou Nano Science and Technology
  5. Innovative Research Teams of Jiangsu Higher Education Institutions
  6. Priority Academic Program Development of Jiangsu Higher Education

向作者/读者索取更多资源

Ruthenium nanoparticles modified on silicon nanowires (Ru/SiNWs) were prepared by directly reducing Ru ions with Si-H bonds. The composites with different contents of Ru (denoted as Ru/SiNW-x, x means the relative molar ratio of Ru to SiNW) were evaluated as electrocatalysts for the hydrogen evolution reaction (HER). Ru/SiNW-42.9 showed an excellent electrocatalytic activity in the oxygen-free 0.5 M H2SO4 medium. The Tafel slope of Ru/SiNW-42.9 was 81 mV/decade, indicating that its catalytic effect was even better than pure Ru particles. SiNWs modified with proper content of Ru may be a promising electrocatalyst for HER. (C) 2015 Elsevier B.V. All rights reserved.

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