期刊
ENERGY & ENVIRONMENTAL SCIENCE
卷 12, 期 1, 页码 273-280出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ee02555j
关键词
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资金
- National Natural Science Foundation for Distinguished Young Scholars of China [51625204]
- National Natural Science Foundation of China [51502319]
- Qingdao Science and Technology Program [17-1-1-26-jch]
- Key Research Program of the Chinese Academy of Sciences [KFZD-SW-414]
- 135 Projects Fund of CAS-QIBEBT Director Innovation Foundation
- Key Scientific and Technological Innovation Project of Shandong [2017CXZC0505]
5 V lithium ion batteries (LIBs) are promising candidates for high energy density batteries. However, conventional carbonate-based liquid electrolyte is vulnerable to oxidative decomposition caused by free radical attack, which leads to poor cycling performance of the 5 V LIBs. Herein, we present a novel strategy based on the free radical scavenging effect to suppress the electrolyte decomposition of 5 V class batteries composed of LiNi0.5Mn1.5O4 (LNMO) cathodes and carbonate-based electrolyte. Our strategy is to scavenge the free radicals during the charging process at the cathode interface by adopting a renewable biomass lignin binder with numerous phenol groups, which can significantly suppress the free radical chain reaction and subsequently generate a compatible multi-dimensional interphase between the electrode and electrolyte. The lignin based electrode exhibited a capacity retention of 94.1% after 1000 cycles, which is significantly higher than that of its PVDF counterpart (46.2%). This work represents a milestone contribution to the strategy for resolving the interfacial issue of high voltage cathode materials, initiating a big step in boosting 5 V batteries.
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