期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 7, 期 5, 页码 2253-2260出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta09439j
关键词
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资金
- National Natural Science Foundation of China [21665020]
- Natural Science Foundation of Inner Mongolia Autonomous Region [2018BS02004]
- Program of Higher-level Talents of Inner Mongolia Agricultural University [NDYB2016-03]
This study demonstrates the synthesis of an efficient photocatalyst, CuO/TiO2 heterojunction, for selective aerobic photo-oxidation of methanol to methyl formate. The CuO nanoparticles (size: 3.5 +/- 1.0 nm) are particularly deposited at the {101} facet of anatase TiO2 nanosheets to minimize recombination of photo-generated electrons/holes. The photocatalysts are characterized by different methods, including powder X-ray diffraction (XRD), transmission electron microscopy (TEM), UV-vis spectroscopy, X-ray photoelectron spectroscopy (XPS), photoluminescence spectroscopy, and hydrogen temperature-programmed reduction (H-2-TPR). The heterojunction catalysts exhibit an excellent photocatalytic performance under mild conditions (i.e., 25-45 degrees C and gas reactions under UV irradiation with a wavelength of 365 nm) for the selective photo-oxidation of methanol using 0.5 vol% oxygen (O-2) as an oxidizing agent. The 5 wt% CuO/TiO2 photocatalyst exhibits a decent 95% methanol conversion with over 85% selectivity towards the formation of methyl formate. The by-product of the reaction is found to be merely CO2, which can be readily eliminated from the product. The formation rate for the methyl formate is 10.8 mmol g(-1) h(-1) at 25 degrees C, which is considerably higher than that for the corresponding CuO and TiO2 nanosheets as well as for conventional catalysts. The superior catalytic activity of the CuO/TiO2 is associated with its unique electronic structure and the synergistic effects at the interface of the photocatalysts' components. The results of this study offer guidelines for design of a new synthetic strategy for preparation of efficient photocatalysts for selective oxidation of methanol to methyl formate and related reactions.
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