期刊
ELECTROANALYSIS
卷 27, 期 3, 页码 591-594出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201400596
关键词
Ion-selective electrode; ISE; Ion-to-electron transduction; Solid-contact ISE; Constant-potential coulometry
Solid-contact ion-selective electrodes (SC-ISEs) are traditionally employed as potentiometric sensors, where the ion activity is related to the zero-current potential of the sensor versus the reference electrode. In this communication, an alternative ion-to-electron transduction principle for SC-ISEs is introduced. The suggested signal transduction principle resembles constant-potential coulometry utilizing the redox capacitance of the internal solid contact in order to convert changes in ion concentration (activity) into electrical current and charge. This short communication provides proof-of-concept for the suggested signal transduction method for SC-ISEs utilizing poly(3,4-ethylenedioxythiphene) (PEDOT) as the solid contact that was coated with a cation-sensitive polymeric membrane.
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