期刊
RSC ADVANCES
卷 9, 期 6, 页码 3403-3406出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ra09784d
关键词
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资金
- Science Technology Program Project of Guangdong Province [2016B020204005]
- Natural Science Foundation of Guangdong Province [2016A030313387]
- China Postdoctoral Science Foundation [2018M643105]
DMSO was found to activate arylisothiocyanates for self-nucleophilic addition. A subsequent intramolecular C-H sulfurization catalyzed by PdBr2 enables access to a wide range of 2-aminobenzothiazole derivatives in moderate to good yields. This is the first example of a DMSO-mediated Pd-catalyzed synthesis of 2-aminobenzothiazoles through cyclization/C-H sulfurization of two isothiocyanates.
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