期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 251, 期 -, 页码 1-8出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2017.05.034
关键词
Periodic mesoporous organosilica; PMO; Bifunctional; L-serine; Aldol; Biomass
类别
资金
- FWO-Flanders [G.0068.13]
Periodic mesoporous organosilica materials (PMOs) offer unique possibilities towards catalysis due to their high stability and tunable organic bridges. Moreover, the presence of the organic bridges make them, in comparison with the traditional silica materials, much more robust in an aqueous environment. As a result, these materials can be applied as catalysts for the valorization of biomass-based resources which are, typically, performed in the presence of water. In this work, we post-synthetically modified benzene bridged PMO with L-serine, thus obtaining a bifunctional PMO bearing a primary amine with an alcohol group on the beta-carbon. The promoting effect of the alcohol, in combination with the amine as a base catalyst, is beneficial in the aldol condensation of acetone and 4-nitrobenzaldehyde. Thorough characterization, including a solid state NMR study, of the L-serine modified PMO was performed as well as a successful catalytic test in an aqueous environment. We obtained a TOF value of 1.61 x 10(-4) +/- 0.08 x 10(-4) s(-1) and a high selectivity towards the aldol product. (C) 2017 Elsevier Inc. All rights reserved.
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