期刊
CHEMICAL SCIENCE
卷 10, 期 6, 页码 1802-1806出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8sc04505d
关键词
-
资金
- NSFC [21672033, 21831002]
- Jilin Province Natural Science Foundation [20160520140JH, 20160519003JH]
- Ten Thousand Talents Program
A copper-catalyzed asymmetric reductive allyl-allyl cross-coupling reaction of allenes with allylic phosphates wherein allenes were used as allylmetal surrogates has been achieved for the first time. This protocol provides an efficient and straightforward route to optically active 1,5-dienes in a highly enantioselective and site-specific fashion. Furthermore, all-carbon quaternary stereogenic centers could also be constructed with this protocol. The versatility of the products is demonstrated through a diverse array of further transformations of the enantioenriched 1,5-dienes.
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