期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 240, 期 -, 页码 216-226出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2016.11.022
关键词
Biomass chitin; Graphitic C3N4; Loofa sponge-like architectures; Mesoporous nanosheets; Bifunctional catalyst
类别
资金
- National Natural Science Foundation of China [51271012]
- Academic Excellence Foundation of BUAA for PhD Students
- School of Materials Science and Engineering of Beihang University
To accelerate the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in the field of air based energy technologies, efficient low-cost bifunctional catalysts are highly desired. In this paper, biomass chitin-derived N-doped carbon (C-Chitin)/graphitic C3N4 (g-C3N4) composites have been designed and fabricated via an ultralow-cost route including the low-temperature dissolution of biomass chitin and the subsequent carbonization. The C-Chitin/g-C3N4 composites exhibit well-designed loofa sponge-like three-dimensional (3D) network architectures assembled with massive interconnected ultrathin mesoporous nanosheets. Benefiting from the well-designed morphology and unique mesoporous structure with a high surface density of catalytic active sites, as well as the incorporation of N-doped carbon with g-C3N4, the C-Chitin/g-C3N4 composites exhibit pronounced ORR activity (4-electron pathway), superior OER activity (much lower onset potential and higher current density than Pt/C), excellent tolerance to methanol crossover and high durability toward both ORR and OER. Especially, the obtained C-Chitin/g-C3N4 composites with 20 wt % addition of g-C3N4 exhibit a potential gap of 0.90 V between the OER potential at a current density of 10 mA cm(-2) and the ORR half wave potential, which is even higher than some highly active metal catalysts including noble-metals, thus holding great promise as low-cost metal-free bifunctional catalysts for efficient ORR and OER. (C) 2016 Elsevier Inc. All rights reserved.
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