期刊
ELECTROANALYSIS
卷 28, 期 4, 页码 663-670出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201500512
关键词
crown ether-modified sensors; electrochemical grafting; heavy metal; stripping voltammetry; artificial neural network
资金
- Spanish Ministry of Science and Innovation (MINECO) [CTQ2013-41577-P, CTQ2012-32863]
- Catalonia program ICREA Academia
A three-sensor array consisting of a graphite-epoxy composite electrode (GEC), 4-carboxybenzo-18-crown-6-GEC and 4-carboxybenzo-15-crown-5-GEC was employed for the simultaneous determination of Cd(II), Pb(II) and Hg(II) by differential pulse anodic stripping voltammetry (DPASV). Sensors were firstly studied for the determination of Hg(II); secondly, peak current responses confirmed that all sensors showed differentiated response for the three considered metals. A response model was developed to resolve mixtures of Cd(II), Pb(II) and Hg(II) at the mu g L-1 level; Discrete Wavelet Transform was selected as preprocessing tool and artificial neural network used for the modelling of the obtained responses.
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