期刊
ORGANIC CHEMISTRY FRONTIERS
卷 6, 期 4, 页码 447-450出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo01192c
关键词
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资金
- National Natural Science Foundation of China [21421002, 21302207, 21871283]
- Science and Technology Commission of Shanghai Municipality [17ZR1437000]
- Foundation of Science and Technology on Sanming Institute of Fluorochemical Industry [FCIT201701BR]
- Henan Province Science and Technology Open Cooperation Program [18210600017]
An intermolecular oxidative radical fluoroalkylfluorosulfonylation reaction of unactivated alkenes with convenient and commercially available (fluoroalkyl) trimethylsilane, silver fluoride, sulfur dioxide and N-fluorobenzenesulfonimide (NFSI) is described. This transformation efficiently affords various fluoroalkyl- containing alkyl sulfonyl fluorides with good functional group tolerance under mild conditions. Silver fluoroalkyl complexes as the fluoroalkyl radical source generated from (fluoroalkyl) trimethylsilane and silver fluoride may be the key intermediate.
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