期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 10, 页码 1386-1389出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc08841a
关键词
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资金
- JICA FRIENDSHIP Project under the Collaboration Kick-starter Programme (CKP)
- CSIR
- UGC India
We report the development of a facile protocol for the deoxygenative hydroboration of aliphatic and aryl carboxylic acids to afford corresponding primary alcohols under solvent-free and catalyst-free conditions. The reaction proceeds under ambient temperature exhibits good tolerance towards various functional groups and generates quantitative yields. The plausible mechanism involves the formation of Lewis acid-base adducts as well as the liberation of hydrogen gas.
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