期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 7, 期 8, 页码 3544-3551出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ta10925g
关键词
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资金
- EPSRC [EP/L018330/1, EP/K002252/1]
- University College London
- China Scholarship Council
- EPSRC [EP/L018330/1, EP/K002252/1] Funding Source: UKRI
A facile and controllable low-temperature (450 degrees C) route is reported to produce ultra-small Co3O4/Co nanoparticles in nitrogen-doped hyperporous graphenic networks (Co3O4/Co@N-G-450). Firstly, amonolayer of ZIF-67 nanocrystals is directly grown in thermal-shock exfoliated graphene networks (EGO) of suitable porosity and porewidths. Later, the ZIF-67 is etched by targeting the small concentrations of residual oxygen functionalities on EGO (approximate to 13 atom%) under a nitrogen atmosphere at 450 degrees C. Therefore, the partial gasification of ZIF-67 followed by oxidation of the resultant open cobalt metal centres produces a highly active nanophase of Co3O4/Co@N-G in a mass yield of >65 wt%. The as-synthesised Co3O4/Co@N-G-450 catalyst, without any further acid washing or oxidation process, exhibits an outstanding ORR performance with a high onset (0.962 V vs. RHE) and half-wave (0.808 V vs. RHE) potential as well as limiting current density (5.2 mA cm(-2)) in 0.1 M KOH solution. These merits are comparable to those of commercial Pt/C and many ZIF-derived catalysts, synthesised under extended and complex chemical treatment. Moreover, the catalyst also exhibits fast reaction kinetics with a dominant 4-electron reaction pathway and high durability.
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