期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 16, 页码 2293-2296出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc09853k
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资金
- German Research Council (DFG) [TE1101/2-1]
- Fonds der Chemischen Industrie
- Daimler and Benz Foundation
A simple and air-stable copper(I)/N-heterocyclic carbene complex enables the catalytic hydrogenation of enoates and enamides, hitherto unreactive substrates employing homogeneous copper catalysis and H2 as a terminal reducing agent. This atom economic transformation replaces commonly employed hydrosilanes and can also be carried out in an asymmetric fashion.
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