期刊
ANALYST
卷 144, 期 4, 页码 1260-1264出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8an01155a
关键词
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资金
- National Natural Science Foundation of China [21202134, 11447215, 21504073]
- Sichuan Youth Science & Technology Foundation [2016JQ0055]
- Longshan academic talent research supporting program of SWUST [18LZX308, 18LZX446]
- China Scholarship Council
A novel fluorescent probe for Pd2+ based on the BODIPY fluorophore exploiting the PET (Photoinduced Electron Transfer) mechanism was designed and successfully synthesized. The fluorescent probe 1 was prepared by introducing m-bisimidazolylbenzene which was connected by phenyl acetylene to the BODIPY dye at the meso position. It exhibited a rapid response and high sensitivity and selectivity toward Pd2+. Probe 1 presented a rapid quenched fluorescence response in aqueous buffer media (pH 5.5) and the detection limit estimated from the titration results was 2.9 x 10(-7) M. Meanwhile, other common metal ions did not interfere with the recognition process. The DFT calculation proved that coordination of bisimidazole ligands with Pd2+ effectively decreases the LUMO energy of m-bisimidazolylbenzene which was located between the HOMO and LUMO energies of the BODIPY dye leading to fluorescence quenching via the d-PET mechanism.
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