期刊
RSC ADVANCES
卷 9, 期 10, 页码 5282-5287出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ra08344d
关键词
-
资金
- element strategy initiative of MEXT Japan
- JSPS KAKENHI [16K05934, 16H06441]
- [2014S06]
- Grants-in-Aid for Scientific Research [16K05934] Funding Source: KAKEN
Strontium lithium orthosilicate hydride Sr2LiSiO4H was synthesized by the reaction of Sr2SiO4 with LiH at 700 degrees C in a H-2 rich atmosphere. Rietveld refinement of the neutron powder diffraction pattern revealed that Sr2LiSiO4H is isostructural to Sr2LiSiO4F (space group P2(1)/m) and its channel-like structure preferentially accommodates H- ions over F- ions. In addition, Sr2LiSiO4H is stable in air and its Eu2+-doped analog exhibits yellow photoluminescence with an emission band at 544 nm and a broad excitation band ranging from 250 to 450 nm. These bands were observed in the longer wavelength region when compared with those displayed by Sr2LiSiO4F:Eu2+. The red shift, which is induced by H- substitution, is consistent with the constrained density functional theory calculations, predicting the photo-excitation and emission energies of 4f-5d transitions. The present study reports the synthesis of stable oxyhydrides acting as phosphor hosts for rare earth ions. The phosphor hosts exhibit large nephelauxetic effects owing to the presence of H- ligands.
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