期刊
SYNOPEN
卷 3, 期 1, 页码 21-25出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1611722
关键词
oxaziridine; Davis' oxaziridine; sodium hypochlorite; sodium hypochlorite pentahydrate; N-sulfonylimine; oxidation
N-Sulfonyloxaziridines (Davis' oxaziridines) can be synthesized by reacting the corresponding N-sulfonylimines with aqueous sodium hypochlorite in acetonitrile without any catalyst. The pH of the aqueous sodium hypochlorite is crucial to obtain the product in high yield. Optimized conditions are presented that allow synthetically useful Davis' oxaziridines to be easily obtained in up to 90% yields from the corresponding imines by using inexpensive, stable, environmentally friendly sodium hypochlorite pentahydrate crystals as the oxidant, with high reproducibility.
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