期刊
CRYSTENGCOMM
卷 21, 期 9, 页码 1358-1362出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ce02153h
关键词
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资金
- Natural Science Foundation of Jiangsu Province [BK20181001, KH17025]
- National Natural Science Foundation of China [21702213, 21302072]
- PAPD of Jiangsu Higher Education Institution
- TAPP of Jiangsu Higher Education Institution
- Natural Science Foundation of Xuzhou City [BK20181001, KH17025]
Here we report the facile preparation of a urea-containing UiO-68 isoreticular zirconium metal-organic framework (MOF) with mixed dicarboxylate struts by utilizing a microwave-assisted heating method. It can work as an efficient hydrogen-bond-donating heterogeneous catalyst for Henry reactions of benzaldehydes and nitroalkanes. This mixed strut MOF exhibits improved catalytic activity compared to the pure urea-functionalized linker based analogue.
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