期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 7, 期 5, 页码 1237-1245出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8tc04890h
关键词
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资金
- National Natural Science Foundation of China [21664015, 21865038, 21602195]
- Program for Innovative Research Team (in Science and Technology) in University of Yunnan Province [2018FY001(-012)]
Novel benzothiadiazole-based bolaamphiphiles comprising a donor-acceptor-donor (thiophene-benzothiadiazole-thiophene) -conjugated rod, two diol groups at the terminals and two alkyl chains at the lateral positions can self-assemble into square honeycomb LC phases and helical gel structures in organic solvents. The square columnar phases should have 4 molecules in each unit cell and 2 molecules in each cell wall with the c-parameter (intermolecular distance) varying from compound to compound. The UV-vis spectra of these red emissive BTD-based bolaamphiphiles covered almost the whole visible range with a relatively low band gap. Most interestingly, white light with CIE coordinates (0.30, 0.33) was obtained by doping this BTD-based bolaamphiphile with a blue emissive dithiophene bolaamphiphile and yellow-green emissive tetrathiophene bolaamphiphile.
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