期刊
ENERGY & ENVIRONMENTAL SCIENCE
卷 12, 期 2, 页码 615-623出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ee02836b
关键词
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资金
- US National Science Foundation [1438198]
- Maryland NanoCenter
- AIM Lab
- NSF
- Multidisciplinary University Research Initiative (MURI) grant
- Div Of Chem, Bioeng, Env, & Transp Sys
- Directorate For Engineering [1438198] Funding Source: National Science Foundation
Potassium-ion batteries (PIBs) have been considered as promising alternatives to lithium-ion batteries due to potassium's high natural abundance of 2.09 wt% (vs. 0.0017 wt% for Li) and K/K+ having a low redox potential of -2.93 V (vs. -2.71 V for Na/Na+). However, PIB electrodes still suffer huge challenges due to the large K-ion radius and slow reaction dynamics. Herein, we report a high-capacity Sb@CSN composite anode with Sb nanoparticles uniformly encapsulated by a carbon sphere network (CSN) for PIBs. First-principles computations and electrochemical characterization confirm a reversible sequential phase transformation of KSb2, KSb, K5Sb4, and K3Sb during the potassiation/depotassiation process. In a concentrated 4 M KTFSI/EC + DEC electrolyte, the Sb@CSN anode delivers a high reversible capacity of 551 mA h g(-1) at 100 mA g(-1) after 100 cycles with an extremely slow capacity decay of only 0.06% per cycle from the 10th to 100th cycle; when at a high current density of 200 mA g(-1), the Sb@CSN anode still maintains a capacity of 504 mA h g(-1) after 220 cycles. The Sb@CSN anodes demonstrate one of the best electrochemical performances for all K-ion battery anodes reported to date. The exceptional performance of Sb@CSN should be attributed to the efficient encapsulation of small Sb nanoparticles in the conductive carbon network as well as the formation of a robust KF-rich SEI layer on the Sb@CSN anode in the concentrated 4 M KTFSI/EC + DEC electrolyte.
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