期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 17, 期 10, 页码 2725-2733出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ob00081j
关键词
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资金
- National Natural Science Foundation of China [21272074, 21871087]
- Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT)
A highly atom-economical protocol for the synthesis of tetrasubstituted furans has been developed. This process is realized through the tandem reactions of Cs2CO3 promoted C-C s-bond activation of a-aryl ketones followed by Zn-catalyzed intramolecular cyclization. This represents the first example for the preparation of tetrasubstituted furans through rearrangement of molecular skeletons and subsequent transformations. Mild reaction conditions and readily accessible starting materials make the protocol attractive in organic synthesis.
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