期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 19, 页码 2793-2796出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc00307j
关键词
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资金
- NSFC [21425205, 21672067]
- 973 Program [2015CB856600]
- Program of Eastern Scholar at Shanghai Institutions of Higher Learning
- China Postdoctoral Science Foundation [2017M610236]
A novel nickel-catalyzed alkyl-alkyl cross coupling of non-activated secondary alkyl bromides with aldehydes via hydrazone intermediates has been developed. Aldehydes as alkyl carbanion equivalents replace traditional organometallic reagents. This coupling occurs on the carbon of the hydrazone rather than the nitrogen. In addition, non-activated primary and tertiary alkyl bromides also undergo the cross-coupling reaction to form new C(sp(3))-C(sp(3)) bonds in moderate yields.
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