期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 19, 页码 2837-2840出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc00357f
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资金
- SERB, DST, India [PDF/2016/002324]
- DST, Govt of India [MR-2015/001019, TRC-DST/C.14.10/16-2724]
- JNCASR
A metal free topological approach is demonstrated to mimic the photophysical properties of natural gfp by synthesizing two gfp chromophore integrated conjugated microporous polymers (o-HBDI-TEB-CMP and o-MBDI-TEB-CMP). Interestingly, owing to the structural rigidity, the emission ((em) = 515 nm) and excited state lifetime (4.1 ns) of hydroxy substituted o-HBDI-TEB-CMP are found to be similar to the natural gfp. The crucial role of the -OH group for the green emission is further supported by -OMe substituted o-MBDI-TEB-CMP ((em) = 440 nm) and also validated theoretically.
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