期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 22, 页码 3199-3202出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc00490d
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资金
- Deutsche Forschungsgemeinschaft through the International Research Training Group Selectivity in Chemo-and Biocatalysis
- National Science Foundation OISE through IRES: Training Next Generation Researchers in Advanced Magnetic Resonance at Chemistry Interfaces [1658652]
- Office Of The Director
- Office Of Internatl Science &Engineering [1658652] Funding Source: National Science Foundation
A magnesium hydride cation [(L)MgH](+) supported by a macrocyclic ligand (L = Me(4)TACD; 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclo-dodecane) has been prepared by partial protonolysis of a mixed amide hydride [(L)MgH2Mg{N(SiMe3)(2)}(2)] and shown to undergo a variety of reactions with unsaturated substrates, including pyridine.
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