期刊
CHEMICAL SCIENCE
卷 10, 期 11, 页码 3231-3236出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8sc05445b
关键词
-
资金
- NSF (NSF CAREER Award) [1254636]
- NIH [1R01GM125791-01A1]
We have developed a nickel-catalyzed hydroarylation of alkenes using aryl halides as coupling partners. Excellent anti-Markovnikov selectivity is achieved with aryl-substituted alkenes and enol ethers. We also show that hydroarylation occurs with alkyl substituted alkenes to yield linear products. Preliminary examination of the reaction mechanism suggests irreversible hydrometallation as the selectivity determining step of the hydroarylation.
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