期刊
MATTER AND RADIATION AT EXTREMES
卷 4, 期 2, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.5086310
关键词
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资金
- National Science Associated Funding (NSAF) [U1530402]
- Natural Science Foundation of China [11874076]
- Science Challenging Program [JCKY2016212A501]
- Postdoctoral Science Foundation [2015M572499]
Polymerization of fullerenes is an interesting topic that has been studied for almost three decades. A rich polymeric phase diagram of C-60 has been drawn under a variety of pressure P and temperature T conditions. Knowledge of the targeted preparation and structural control of fullerene polymers has become increasingly important because of their utility in producing novel fullerene-based architectures with unusual properties and potential applications. This paper focuses on the polymeric phases of fullerenes and their derivatives under high P and/or high T. First, the polymerization behavior and the various polymeric phases of C-60 and C-70 under such conditions are briefly reviewed. A summary of the polymerization process of intercalated fullerenes is then presented, and a synthetic strategy for novel structural and functional fullerene polymers is proposed. Finally, on the basis of the results of recent research, a proposal is made for further studies of endohedral fullerenes at high P. (C) 2019 Author(s).
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