期刊
INORGANIC CHEMISTRY FRONTIERS
卷 6, 期 2, 页码 473-476出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qi01143e
关键词
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资金
- National Natural Science Foundation of China (NSFC) [51772142]
- Development and Reform Commission of Shenzhen Municipality (Novel Nanomaterial Discipline Construction Plan)
- Shenzhen Science and Technology Innovation Commission [JCYJ20170412152528921, KQJSCX20170328155428476]
- National Natural Science Foundation of China [21471160]
- Taishan Scholar Program of Shandong Province of China
Sn-Based materials are considered as promising anode materials for lithium ion batteries due to their high theoretical capacities; however, aggregation of electrochemically active particles and pulverization resulting from huge volume changes during alloying/dealloying severely limit their performance. To solve these problems, nanosized and hollow structures have been proposed. Herein, uniform solid Sn nanoparticles and hollow/amorphous SnOx nanospheres are prepared accordingly and their electrochemical performances as anode materials in lithium ion batteries have been evaluated. Uniform solid Sn nanoparticles deliver a capacity of 416.4 mA h g(-1) for 400 cycles at a current of 500 mA g(-1), corresponding to a high capacity retention of 81.1%. Furthermore, hollow/amorphous SnOx nanospheres show a high capacity retention of 81.3% for 400 cycles at a current of 500 mA g(-1) and exhibit a good rate capability (retains 58.0% of the capacity at 1000 mA g(-1) with respect to 100 mA g(-1)). It is believed that their good electrochemical performances mainly originate from their small sizes (<20 nm) and unique nanoarchitectures.
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