期刊
ORGANIC CHEMISTRY FRONTIERS
卷 6, 期 6, 页码 841-845出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo01412d
关键词
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资金
- National Natural Science Foundation of China [21572195, 21702175]
- 1000 Youth Talents Plan
- Scientific and Technological Innovation Leading Talent Reserve of Xinjiang Uygur Autonomous Region [wr2016cx0145]
- Natural Science Foundation of Xinjiang University [BS160219]
B(2)pin(2)-catalyzed oxidative cleavage of the C?C double bond of an olefin with molecular oxygen as the oxidant and oxygen source has been developed. Various diaryl ketone, diketone, triketone and estrone derivatives were obtained in moderate to excellent yields. The NMP (N-methyl pyrrolidone)-stabilized B-centered radical species was proposed as a possible catalyst.
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