期刊
GREEN CHEMISTRY
卷 21, 期 6, 页码 1412-1416出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8gc03906b
关键词
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资金
- QUILL [FIRB 2010RBFR10BF5 V, PJ_RIC_FFABR_2017_160575, 12/IP/1703]
- MIUR [FIRB 2010RBFR10BF5 V, PJ_RIC_FFABR_2017_160575, 12/IP/1703]
- SFI [FIRB 2010RBFR10BF5 V, PJ_RIC_FFABR_2017_160575, 12/IP/1703]
A new ionic liquid with sugar-based ligand has been prepared and used to coordinate cobalt(ii), at low loading, in an ionic liquid solution. The system obtained reveals magnetic switching and marked thermochromism in solution/polymer films over a convenient temperature range (20-60 degrees C). This system is self-contained, devoid of any volatile substances, and reproducible over multiple thermal cycles. The colour change can be attributed to a change in the coordination geometry from octahedral (pink) at room temperature to tetrahedral (blue) on warming, monitored by Co-59 NMR spectroscopy, which was used for the first time to study the change. This material may find applications in stimuli-responsive smart systems aimed at energy storage applications.
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