4.3 Article

Electrochemical hydrogen peroxide sensor based on carbon supported Cu@Pt core-shell nanoparticles

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ELSEVIER
DOI: 10.1016/j.msec.2017.04.072

关键词

Non-enzymatic hydrogen peroxide sensor; Electrocatalysis; Cu@Pt/C nanocomposites

资金

  1. National Natural Science Foundation of China [21205030]
  2. National Nature Science Foundation of China [51402096]
  3. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing (Wuhan University of Technology) [2015-KF-13]
  4. Natural Science Fund for Creative Research Groups of Hubei Province of China [2014CFA015]

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The Cu@Pt/C nanocomposites have been synthesized via two-step reduction method. Electrochemical observations showed that the Cu@Pt/C had better electrocatalytic activity for the reduction of hydrogen peroxide than Pt/C, with a wide linear range between 0.50 mu M and 32.56 mM, a high sensitivity of 351.3 mu A mM(-1) cm(-2), and a low detection limit of 0.15 mu M (signal/noise = 3). Furthermore, the sensor based on Cu@Pt/C has potential applications due to its excellent long-time stability, good reproducibility and acceptable selectivity. (C) 2017 Elsevier B.V. All rights reserved.

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