期刊
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS
卷 78, 期 -, 页码 185-190出版社
ELSEVIER
DOI: 10.1016/j.msec.2017.04.072
关键词
Non-enzymatic hydrogen peroxide sensor; Electrocatalysis; Cu@Pt/C nanocomposites
资金
- National Natural Science Foundation of China [21205030]
- National Nature Science Foundation of China [51402096]
- State Key Laboratory of Advanced Technology for Materials Synthesis and Processing (Wuhan University of Technology) [2015-KF-13]
- Natural Science Fund for Creative Research Groups of Hubei Province of China [2014CFA015]
The Cu@Pt/C nanocomposites have been synthesized via two-step reduction method. Electrochemical observations showed that the Cu@Pt/C had better electrocatalytic activity for the reduction of hydrogen peroxide than Pt/C, with a wide linear range between 0.50 mu M and 32.56 mM, a high sensitivity of 351.3 mu A mM(-1) cm(-2), and a low detection limit of 0.15 mu M (signal/noise = 3). Furthermore, the sensor based on Cu@Pt/C has potential applications due to its excellent long-time stability, good reproducibility and acceptable selectivity. (C) 2017 Elsevier B.V. All rights reserved.
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