Improved Electrode Performance of Lithium-Excess Molybdenum Oxyfluoride: Titanium Substitution with Concentrated Electrolyte

A titanium-substituted lithium-excess molybdenum oxyfluoride, Li2.1-yTi0.2Mo0.7O2F, is synthesized by mechanical milling and tested as a positive electrode material in a conventional carbonate-based electrolyte or concentrated electrolyte. Reversibility as the electrode material is significantly improved by suppression of dissolution of the molybdenum oxyfluoride on electrochemical cycles. Li2.1-yTi0.2Mo0.7O2F delivers a reversible capacity of 265 mA h g(-1) after 30 cycles at a rate of 50 mA g(-1) with concentrated electrolyte. This finding contributes to the development of high-energy and long-cycle-life rechargeable lithium batteries with lithium-excess metal oxyfluorides in the future.