期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 7, 期 12, 页码 3503-3511出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9tc00465c
关键词
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资金
- National Key Research and Development Program of China [2015CB655002, 2017YFA0204501]
- National Natural Science Foundation of China [61890942, 51525304, U1601651]
Sublimable cationic iridium(iii) complexes achieved by introducing bulky negative counter-ions have shown excellent performance in green-, yellow- and red-emitting devices, revealing their promising future in organic optoelectronic applications. However, the performance of blue-emitting devices remains unsatisfactory. Here, we develop a series of sublimable cationic iridium(iii) complexes with 1-phenyl-1H-pyrazole as the major cyclometalated ligand and demonstrate their high thermal stability, and excellent electrochemical and photophysical properties with high photoluminescence quantum yields up to 93%. We also optimize blue-green-emitting OLEDs based on these complexes, achieving a maximum external quantum efficiency of 5.9% with colour coordinates of (0.19, 0.30) and 11.3% with (0.27, 0.50), respectively, among the best performance of blue- and green-emitting devices based on cationic iridium(iii) complexes.
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