期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 26, 页码 3769-3772出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc01379b
关键词
-
资金
- National Natural Science Foundation of China [21672049]
A palladium-catalyzed enantioselective coupling of 2,5-cyclohexadienyl-substituted aryl iodides and carbon or heteroatom nucleophiles is described. The reaction proceeded via a tandem asymmetric Heck insertion and Tsuji-Trost allylation, enabling the rapid construction of valuable chiral tetrahydrofluorenes by using a chiral H8-BINOL-based phosphoramidite ligand.
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