期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 38, 期 6, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201600741
关键词
hydrogel; light-responsive; self-healing; supramolecular interaction
资金
- Natural Science Foundation of China [21604044]
- Natural Science Foundation of Ningbo [2015A610020, 2016A610047]
- Natural Science Foundation of Zhejiang [LQ14E030002]
- Opening Fund of Beijing National Laboratory of Molecular Science, Postdoctoral Science Foundation of China [2015M581966]
- K. C. Wong Magna Fund in Ningbo University
A self-healing hydrogel is prepared by crosslinking acrylamide with a host-guest macro-crosslinker assembled from poly(beta-cyclodextrin) nanogel and azobenzeneacrylamide. The photoisomerizable azobenzene moiety can change its binding affinity with beta-cyclodextrin, therefore the crosslinking density and rheology property of the hydrogel can be tuned with light stimulus. The hydrogel can repair its wound autonomously through the dynamic host-guest interaction. In addition, the wounded hydrogel will lose its ability of self-healing when exposed to ultraviolet light, and the self-healing behavior can be recovered upon the irradiation of visible light. The utilizing of host-guest macro-crosslinking approach manifests the as-prepared hydrogel reversible and light-switchable self-healing property, which would broaden the potential applications of self-healing polymers.
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