期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 38, 期 16, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201700251
关键词
benzoxazine; dendrimer; thermal curing; triphenylamine
资金
- Ministry of Science and Technology, Taiwan [MOST103-2221-E-110-079-MY3, MOST105-2221-E-110-092-MY3]
A series of thermally polymerizable dendrimers of various generations, equipped with triphenylamine (TPA) and benzoxazine (BZ) groups, is synthesized through facile one-pot Mannich condensations of N-1, N-1-bis(4-aminophenyl) benzene-1,4-diamine (TPA-3NH(2), as the core group), 4-(bis(4-aminophenyl) amino) phenol (TPA-2NH(2)-OH, as the AB(2) branching group), and CH2O in 1,4-dioxane. The ratios of the integrated areas in the H-1 nuclear magnetic resonance spectra of these dendrimers are consistent with the theoretical numbers of protons, suggesting their successful syntheses. Bathochromic shifts of signals are evident in the UV-vis and photoluminescence spectra upon increasing the generation of the TPA-BZ dendrimers, consistent with an increase in the effective conjugation length. The TPA-BZ dendrimers are able to undergo thermal polymerization and display unique optical physical properties, resulting in thermoset TPA networks after thermal ring-opening polymerization.
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