期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 31, 页码 4538-4541出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc00581a
关键词
-
资金
- National Natural Science Foundation of China [21875146, 21501161]
A novel compound with four mixed anions, Y8O(OH)(15)(CO3)(3)Cl, exhibiting an infrequent three-dimensional (3-D) inorganic cationic framework, has been successfully designed and synthesized by introducing -conjugated planar triangular CO3 groups and chloride anions into a rare earth oxide system, which exhibits good balance among its wide UV transmission range, large second harmonic generation (SHG) coefficient and suitable birefringence to meet the phase-matching condition, indicating that the titled compound is a promising short-wave UV nonlinear optical material.
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