期刊
CHINESE JOURNAL OF ORGANIC CHEMISTRY
卷 39, 期 4, 页码 1079-1084出版社
SCIENCE PRESS
DOI: 10.6023/cjoc201811017
关键词
daphniphyllum alkaloid; daphnilactone B; Diels-Alder reaction; Conia-ene reaction; total synthesis
资金
- National Natural Science Foundation of China [21772082]
- Shenzhen Science and Technology Innovation Committee Basic Research Discipline Layout Project and Peacock Technology Innovation [JCYJ20170817110515599, KQJSCX2017072815423320]
- Shenzhen Development and Reform Commission (Discipline Construction Program)
- Shenzhen Peacock Plan [KQTD20150717103157174]
- Shenzhen Nobel Prize Scientists Laboratory Project [C17783101]
The synthesis of the AC ring moiety of daphnilactone B has been achieved through an efficient Diels-Alder reaction and Au-catalyzed Conia-ene reaction in seven steps with 30% overall yield. Our strategies paved the way to the total synthesis of various daphnilactone B-type Daphniphyllum alkaloids.
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