期刊
LANGMUIR
卷 33, 期 17, 页码 4328-4336出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.7b00927
关键词
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资金
- National Natural Science Foundation of China [21373127, 21673129]
- Specialized Research Fund for the Doctoral Program of Higher Education [20130131110010]
The aggregation behavior of quaternary ammonium gemini surfactants (12-s-12) in a protic ionic liquid, ethanolammonium nitrate (EOAN), was investigated by small-angle X-ray scattering, freezefracture transmission electron microscopy, polarized optical microscopy, and rheological measurements. The rarely reported nonaqueous two phases in the ionic liquid were observed at lower 12-s-12 concentrations. The upper phase was composed of micelles, whereas only the surfactant unimers or multimers were detected in the low phase. At higher 12-s-12 concentrations, different aggregates were formed. The lamellar phase was observed in the 12-2-12/EOAN system, whereas the normal hexagonal phases in 12-s-12/EOAN (s = 3, 4, 5, 6, 8) systems and the micellar phase in the 12-10-12/EOAN system were observed. Such a dramatic phase transition induced by the spacer chain length was due to the unique solvent characteristics of EOAN compared to those of water and its counterpart ethylammonium nitrate.
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