期刊
ELECTROCHEMICAL ENERGY REVIEWS
卷 2, 期 2, 页码 277-311出版社
SPRINGERNATURE
DOI: 10.1007/s41918-019-00032-8
关键词
Li-rich layered oxide; Surface coating; Voltage fade; Oxygen activities; Lithium-ion battery
资金
- Australian Research Council (ARC) through the Future Fellowship projects [FT150100109, FT160100251]
- NSFC [51474110]
- Natural Science Foundation of Hubei Province [2018CFB192]
- CSC [201608420205]
Lithium-rich layered oxides (LLOs), also known as Li1+xM1-xO2 or xLi(2)MnO(3)-(1-x)LiMO2 (M=Ni, Co, Mn), have been regarded as some of the highest capacity lithium cathodes and have attracted increasing attention from battery researchers and engineers in recent years. This is because LLOs possess maximum possible capacities of similar to 280 to 310 mAh g(-1) with a high working potential of similar to 3.7 V (vs. Li+/Li-0) and an astounding energy density of similar to 900 Wh kg(-1). Despite these promising properties, these technologically important cathodes have not yet been successfully commercialized due to low initial Coulombic efficiency, poor rate capabilities and gradual capacity/voltage fade during electrochemical cycling as well as further complications from continuous structural changes during cycling. Here, researchers have concluded that these issues mainly originate from the electrochemical activation of Li2MnO3 components, which, although it provides anomalously high capacity performances, also causes associated complex anionic redox activities of O and irreversible structural and phase transformations during charging at potentials greater than 4.5 V (vs. Li+/Li-0). To provide perspectives, this review will summarize various attempts made towards addressing these issues and present the connections between electrochemical properties and structural change. In addition, this review will discuss redox chemistries and mechanistic behaviours during cycling and will provide future research directions to guide the commercialization of LLOs.
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