期刊
CHEMICAL SCIENCE
卷 10, 期 19, 页码 5162-5166出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9sc01356c
关键词
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资金
- German Science Foundation (DFG) [KO 1537/18-1]
- European Research Council (ERC) under the European Union's Horizon 2020 Research and Innovation Programme [741623]
We present a redox-neutral method for the photocatalytic generation of carbanions. Benzylic carboxylates are photooxidized by single electron transfer; immediate CO2 extrusion and reduction of the in situ formed radical yields a carbanion capable of reacting with aliphatic aldehydes as electrophiles giving the Grignard analogous reaction product.
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