4.7 Article

One-step synthesis of single crystalline wedge-shaped Ta3N5 nanoflakes with ultrathin top ends

期刊

CRYSTENGCOMM
卷 21, 期 19, 页码 2980-2984

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ce00092e

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资金

  1. National Natural Science Foundation of China [51872135, 51572121, 21603098, 21633004]
  2. Natural Science Foundation of Jiangsu Province [BK20151265, BK20151383, BK20150580]
  3. Fundamental Research Funds for the Central Universities [021314380133, 021314380084]
  4. Program B for outstanding PhD candidate of Nanjing University [201802B068]

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Wedge- shaped Ta3N5 nanoflakes with ultrathin top ends and preferentially exposed {010} facets were directly grown on a Ta plate via one-step nitridation. The mixed CsI-Cs2CO3 flux controls the growth kinetics of Ta3N5 and possibly has an impact on the dissolving process of Ta.

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