4.7 Article

Ligand assisted electrocatalytic water oxidation by a copper( II) complex in neutral phosphate buffer

期刊

CHEMICAL COMMUNICATIONS
卷 55, 期 38, 页码 5483-5486

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc00971j

关键词

-

资金

  1. DST (SERB) of India [YSS/2015/000878]

向作者/读者索取更多资源

The electrocatalytic water oxidation activity of a copper(ii) complex, 1, [Cu(L1H)(L-1)(OH2)](ClO4), with a redox active aryl oxime ligand, L1H [L1H = 1-(pyridin-2-yl) ethanone oxime] has been investigated. Complex 1 shows a remarkably high turnover frequency of approximate to 100 s(-1) in neutral phosphate buffer at about 675 mV overpotential with approximate to 94% faradaic efficiency. Electrochemical analysis suggests the involvement of a ligand moiety in a proton-coupled-electron-transfer (PCET) step during the catalytic cycle of complex 1, which in turn provides a route for accumulation of high oxidizing equivalents at the reaction center.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据