4.7 Article

In situ TEM and half cell investigation of sodium storage in hexagonal FeSe nanoparticles

期刊

CHEMICAL COMMUNICATIONS
卷 55, 期 39, 页码 5611-5614

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02107h

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资金

  1. National Natural Science Foundation of China [11702165, 51702207]
  2. Opening Project of State Key Laboratory of Silicon Materials [SKL2017-07]
  3. Program for Professor of Special Appointment (Young Eastern Scholar Program) at Shanghai Institutions of Higher Learning
  4. Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning and Shanghai Youth Top-Notch Talent Program
  5. Fundamental Research Funds for the Central Universities [2018XZZX001-05]

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A hexagonal FeSe nanoparticle anode with a novel reaction mechanism and mechanical stability may fully facilitate the desirable rate capability and cycling performance in sodium-ion batteries. In situ TEM reveals that hexagonal FeSe nanoparticle transition to the Fe and Na2Se phase during sodiation, while the products transform to the tetragonal FeSe phase after desodiation.

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