4.7 Article

Hydrogen atom transfer from 1,2-and 1,3-diols to the cumyloxyl radical. The role of structural effects on metal-ion induced C-H bond deactivation

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CHEMICAL COMMUNICATIONS
卷 55, 期 36, 页码 5227-5230

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc01879d

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  1. University of Rome Tor Vergata'' [E81I18000220005]

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Strong C-H bond deactivation toward HAT has been observed in the reactions of the cumyloxyl radical with 1,2- and 1,3-diols, following addition of Li+ and Ca2+. Weaker effects have been observed with Mg2+. The role of the substrate structure and of the metal ion in the formation of Lewis acid-base complexes is discussed.

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