期刊
KOREAN JOURNAL OF CHEMICAL ENGINEERING
卷 34, 期 4, 页码 1081-1090出版社
KOREAN INSTITUTE CHEMICAL ENGINEERS
DOI: 10.1007/s11814-017-0015-3
关键词
Activated Carbon; Thermal Treatment; Adsorption; Carbon Paste Electrode; Phenols
The adsorptive properties of thermally treated activated carbon at 1,500 and 1,800 A degrees C were investigated. The adsorption kinetics and adsorption efficiency of phenol, 4-chlorophenol and 2,4-dichlorophenol from aqueous solutions were examined. The adsorption kinetic data were analyzed using the pseudo-first and pseudo-second order models, while the equilibrium adsorption data were described by the Langmuir and Freundlich isotherms. The adsorption rate and efficiency increased in the order: phenol < 4-chlorophenol < 2,4-dichlorophenol. The activated carbons were also used for the modification of the carbon paste electrodes for the detection of the phenols based on the differential pulse voltammetry. Compared to the non-modified electrode, all the new paste electrodes showed a significantly greater sensitivity for the detection of the phenols. The signal response was closely related to the porosity of the materials used, and increased with an increase in the adsorption ability and the specific surface area of the modifiers.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据