期刊
MATERIALS CHEMISTRY FRONTIERS
卷 3, 期 4, 页码 702-708出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qm00669e
关键词
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资金
- National Natural Science Foundation of China [51573077, 21875111]
- Jiangsu Province Natural Science Foundation [BK20180496]
- 333 Project to Cultivate High Level Talents in Jiangsu Province
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Six Talent Peaks Project in Jiangsu Province
Two novel dithieno[3,2-b:2,3-d]pyrrol fused electron acceptors (FREAs) with branched alkyl side-chains have been developed. With 2-ethylhexyl and 2-butyloctyl introduced on the N-position of the pyrrol unit, the sidechain engineered acceptors (INPIC-EH and INPIC-BO) were evaluated for organic solar cells (OSCs) by comparison with our reference INPIC-4F bearing a linear octyl chain. The optoelectronic properties of the FREAs and their bulk-heterojunction (BHJ) with a PBDB-T donor for OSCs are systematically studied. All FREAs exhibit similar absorption spectra and energy levels. Notably, the charge dissociation process, charge mobility, and morphology of the BHJ films make a distinct difference. Consequently, the OSCs constructed with INPIC-EH and INPIC-BO delivered a power conversion efficiency (PCE) of 11.9% and 11.2%, lower than that of INPIC-4F devices (13.1%). The lower short-circuit current density (J(SC)) and fill factor (FF) of INPIC-EH and INPIC-OB based devices are attributed to unfavorable morphology of the active layers and more bimolecular recombination and unbalanced charge transport. Our investigation demonstrates that side-chain engineering on FREAs has a great impact on the morphology of blends and thus the photovoltaic properties of their OSCs.
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