期刊
KINETICS AND CATALYSIS
卷 60, 期 1, 页码 62-68出版社
PLEIADES PUBLISHING INC
DOI: 10.1134/S0023158419010063
关键词
fatty acid methyl esters; epoxidation; solvent effects; titanium silicate
资金
- Russian Foundation for Basic Research [18-33-00550]
- Program of development of Flagship University of Russia for Nizhny Novgorod State Technical University
- Ministry of Education and Science of the Russian Federation [10.2326.2017/PP]
Solvent effects in epoxidation of fatty acid methyl esters (FAMEs) by hydrogen peroxide on a TS-1 heterogeneous catalyst is studied for the first time. It is found that the catalytic activity of TS-1 (titanium silicalite) is significantly affected by the polarity of the solvent and its proton-donor-acceptor properties. The highest activity and selectivity is ensured by the use of solvents that are not donors of hydrogen bonds. The best results were achieved when acetonitrile was used as a solvent: the conversion of FAMEs after 6 h was 77%, and the selectivity to epoxide was 61%.
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