期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 43, 页码 6010-6013出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc03004b
关键词
-
资金
- National Natural Science Foundation of China [21871053, 21532001]
A sulfonylation reaction of 4-substituted Hantzsch esters, DABCO center dot(SO2)(2), and electron-deficient alkenes at room temperature in the presence of photoredox catalysis under visible light irradiation is described. Not only (E)-chalcones but also (vinylsulfonyl) benzene and 2-vinylpyridine are all suitable substrates in the transformation. This sulfonylation reaction under mild conditions shows a broad substrate scope with a good functional group compatibility. A plausible mechanism is proposed, which shows that the 4-substituted Hantzsch esters would be radical reservoirs under photoredox catalysis. The alkyl radical generated in situ from the 4-substituted Hantzsch ester would be trapped by sulfur dioxide to produce an alkylsulfonyl radical, which would then undergo further transformation leading to the final outcome.
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