4.7 Article

PdCl2(CH3CN)2-catalyzed regioselective C-H olefinations of 2-amino biaryls with vinylsilanes as unactivated alkenes

期刊

CHEMICAL COMMUNICATIONS
卷 55, 期 44, 页码 6229-6232

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc02199j

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  1. National NSF of China [21503060, 21472031, 51303043]

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The first example of palladium-catalyzed chelation-assisted C-H olefination of 2-amino biaryls using readily available vinylsilanes as unactivated olefinating reagents has been developed, affording valuable arylated vinylsilane compounds in moderate to excellent yields and with exclusive (E)-selectivities.

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