期刊
ORGANIC CHEMISTRY FRONTIERS
卷 6, 期 11, 页码 1734-1737出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9qo00197b
关键词
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资金
- CREST-JST, Program for Leading Graduate Schools Integrative Graduate Education and Research Program in Green Natural Sciences in Nagoya University
- WISE Program (Doctoral Program for World-leading Innovative & Smart Education) Graduate Program of Transformative Chem-Bio Research in Nagoya University
- JSPS
A diastereoselective borylcyclopropanation of a-MIDA-boryl styrenes with 1,1-diiodoborylmethane is developed using 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) as a catalyst under visiblelight irradiation. The scope of this photocatalytic method is explored, and the utility of the resulting doubly borylated cyclopropanes is demonstrated by the selective transformation of one of the two boryl groups.
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